Product ID:OXYGEN, REFRIGERATED LIQUID, G-102
MSDS Date:05/30/1990
FSC:6830
NIIN:00N010756
MSDS Number: BHGVT

AIRCO GASES

575 MOUNTAIN AVE
MURRAY HILL, NJ 07974
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 908-464-8100

Cage: HO601

AIRCO INC, AIRCO INDUSTRIAL GASES DIV.

MURRAY HILL, NJ 07974-2006 US

Telephone: 800-424-9300(CHEMTREC)

Cage: 00741

FOR SERVICE CNDTNS. FOR ADDNL STORAGE RECOMS,

RTECS: 9999999ZZ

G-4.4. EQUIP TO CONTAIN OXYGEN MUST BE "CLEANED FOR

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REFILLED EXCEPT BY QUALIFIED PRODUCERS OF

RTECS: 9999999ZZ

BEEN FILLED BY OWNER OR WITH HIS/HER (WRITTEN)

RTECS: 9999999ZZ

AND FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

99.6 TO 99.997

CAS: 7782-44-7

RTECS: RS2060000

Fraction By Weight: <99.997%

OSHA PEL N/K

ACGIH TLV: N/K

W/OUT MED ADVICE. IN CASE OF FREEZING/CRYOGENIC

RTECS: 9999999ZZ

OR EVEN TEPID WATER. REMOVE FROM SOURCE OF CONTAM.

RTECS: 9999999ZZ

REFER TO OPHTHALMOLIGIST FOR TREATMENT & FOLLOW UP.

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CYLS. NO SMKNG OR OPEN FLAMES SHOULD BE

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ONLY IN WELL VENT AREAS I/A/W MFR'S & AIRCO/BOC'S

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TRUCKS ARE NEEDED FOR MOVEMENT. FULL & EMPTY CYLS

RTECS: 9999999ZZ

CONSULT COMPRESSED GAS ASSOC PAMPHLETS G-4, P-12,

RTECS: 9999999ZZ

CRYOGENIC LIQ FORM IN ENCLSD SPACE SUCH AS CAR

RTECS: 9999999ZZ

EXPLOSION, ASPHYXIATION OR TOXIC EXPOSURE.

RTECS: 9999999ZZ

COMPOSITES OR KEL-F ARE PREF NON-METALLIC

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: HIGH CONCS (>75%) CAUSE SYMPS
OF HYPEROXIA WHICH CAN LEAD TO PNEUM. HYPEROXIA SYMPS INCL CRAMPS,
NAUS, DIZZ, HYPOTHERMIA, AMBLYOPIA, RESP DFCLTIES, BRADYCARDIA,
FAINTING SPELLS & CONVLS CAPABLE OF LEADING TO DEATH. CONCS
BETWEEN 25-75% PRESENT RISK OF INFLAMM OF ORG MATTER IN BODY. SKIN:
CNTCT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: W/LIQ OR COLD PIPING CONTAINING LIQ
CAUSE TISS FREEZING OR FROSTBT UPON DERMAL CNTCT. FROSTBT EFTS ARE
CHANGE IN COLOR OF SKIN TO GRAY OR WHITE POSS FOLLOWED BY
BLISTERING. EYES: CNTCT W/LIQ PROD MAY CAUSE TISS FREEZING. NOTE:
HLT HAZ DATA IS FOR GASEOUS OXYGEN. ONE VOLUME OF LIQ OXYGEN AT ITS
BP & (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: CALL MD IMMED . INHAL: PROMP MED ATTN IS MANDATORY IN
ALL CASES OF OVEREXP. ASSIST TO UNCONTAMD AREA TO INHALE FRESH AIR.
QUICK REMOVAL FROM CONTAMD AREA IS MOST IMPORTANT. MOVE UNCON PE RS
TO UNCONTAMD AREA & IF BRTHG STOPPED, ADMIN ARTF RESUSCITATION &
SUPPLEMENTAL OXYGEN. FURTHER TREATMENT SHOULD BE SYMP & SUPPORTIVE.
SKIN: FLUSH AFFECTED AREA W/LUKEWARM WATER. DO NOT USE (SUPDAT)

Extinguishing Media:COPIOUS QTYS OF WATER (OR THE SUITABLE
EXTINGUISHING AGENT FOR THE COMBUST MATL) FOR FIRES W/OXYGEN AS THE
OXIDIZER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . IF POSSIBLE, STOP THE FLOW OF OXYGEN WHICH
IS SUPPORTING THE FIRE.
Unusual Fire/Explosion Hazard:ELECTRICAL CLASSIFICATION: NONHAZARDOUS.
VIGOROUSLY ACCELERATES COMBUSTION.

Spill Release Procedures:STATIONARY CUSTOMER SITE VESSELS SHOULD
OPERATE I/A/W MFR'S & AIRCO'S INSTRUCTIONS. DO NOT ATTEMPT TO
REPAIR, ADJUST OR IN ANY OTHER WAY MODIFY OPERATION OF VESSELS. IF
THERE IS MALFUNCTION OR OTHER T YPE OF OPERATION PROB W/VESSEL,
CNTCT MFR IMMED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OXYGEN, REFRIGERATED LIQ IS DELIVERED
INTO STATIONARY, VACUUM-JACKETED VESSELS AT CUSTOMER'S LOCATION OR
IN PORTABLE VACUUM-JACKETED "LIQ" (ING 5)
Other Precautions:LIQ OXYGEN CANNOT BE HANDLED IN CARBON OR LOW ALLOY
STEEL. 18-8 & 18-10 STAINLESS STEEL ARE ACCEPTABLE AS ARE COPPER &
ITS ALLOYS, NICKEL & ITS ALLOYS, BRASS, BRONZE, SILICON ALLOYS,
MONEL, INCONEL & BERYLLIUM. TEFLON, TEFLON (ING 11)

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:MAINTAIN OXYGEN LEVEL IN AIR > 19.5%. USE LOC EXHST TO PVNT
ACCUM OF HIGH CONCS THAT INCR OXYGEN LEVEL IN AIR TO > 23%.
Protective Gloves:LOOSE FITTING AND INSULATED.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 16)
Other Protective Equipment:SAFETY SHOES, SAFETY SHOWER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VP: ABOVE CRITICAL TEMP. EFTS OF OVEREXP: ATM PRESS WILL VAPORIZE INTO
APPROX 860 VOLUMES OF GASEOUS OXYGEN AT 70F (21.1C) & 1 ATM. FIRST
AID PROC: HOT WATER. MD SHOULD SEE PROMPTLY IF CRYOGENIC "BURN "
HAS RSLTD IN BLISTERING OF DERMAL SURF OR DEEP TISS FREEZING. EYES:
NEVER INTRODUCE OINTMENT/OIL INTO EYES (ING 2)

Boiling Pt:B.P. Text:-297F,-183C
Vapor Pres:SUPDAT
Spec Gravity:1.105
Solubility in Water:SLIGHTLY SOLUBLE
Appearance and Odor:A CLEAR, PALE-BLUE LIQUID; ODORLESS.

Stability Indicator/Materials to Avoid:YES
ALL FLAMMABLE MATERIALS.
Stability Condition to Avoid:CONTACT WITH ALL FLAMMABLE MATERIALS.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.